Geometry and stability of graphitic onion-like structures

Novel Graphitic Structures by Design

Graphitic Structures by Design (GSD) is a novel technology for growing graphite in precise patterns from the nano to the macroscale, rapidly (>1 layer/sec), at low temperatures (ca. 500C), and in a single step using ordinary laboratory equipment. The GSD process consists of exposing particular metals (Ni, Pd, Pt, Co), which act as ‘templates’, to a fuel rich combustion environment. As an exampl...

2007: Graphitic Structures By Design: Film formation

The potential applications of new graphitic materials, including carbon nanotubes and carbonized spheres, is limited by both the cost of production and the difficulties of organizing them into final geometries. We have developed a simple, low temperature (ca. 500 C) novel technology based on our discovery that in certain lean burn combustion environments graphite will grow rapidly (>1 graphene ...

Bending modes, elastic constants and mechanical stability of graphitic systems

Graphitic Phase of NaCl. Bulk Properties and Nanoscale Stability.

We applied the ab initio approach to evaluate the stability and physical properties of the nanometer-thickness NaCl layered films and found that the rock salt films with a (111) surface become unstable with thickness below 1 nm and spontaneously split to graphitic-like films for reducing the electrostatic energy penalty. The observed sodium chloride graphitic phase displays an uncommon atomic a...

High Temperature Stability of Onion-Like Carbon vs Highly Oriented Pyrolytic Graphite

The thermodynamic stability of onion-like carbon (OLC) nanostructures with respect to highly oriented pyrolytic graphite (HOPG) was determined in the interval 765-1030 K by the electromotive force (emf) measurements of solid electrolyte galvanic cell: (Low) Pt|Cr3C2,CrF2,OLC|CaF2s.c.|Cr3C2,CrF2,HOPG|Pt (High). The free energy change of transformation HOPG = OLC was found positive below 920.6 K ...